Über geometrische Eigenschaften einer verallgemeinerten stereoskopischen Abbildung

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High resolution and tandem fourier-transform mass spectrometry with californium-252 plasma desorption

For ions formed by plasma desorption (PD) in a Fourier-transform mass spectrometer, high resolution measurements are demonstrated, such as 65,000 (FWHH) for the protonated molecular ion of gramicidin S (MW 1140.7). Resolution is substantially improved by delaying measurements until a significant ion concentration has built up in the cell, and by collisionally deactivating the orbital kinetic energy of the ions. This also makes the ions available for subsequent dissociation steps, so that tandem mass spectrometry can be demonstrated for PD ions. With this for larger ions, collisionally activated dissociation (CAD) is affected with> 85% efficiency. The CAD spectra of (M + Na)⁺ and of fragment ions from the PD of gramicidin S provide structurally useful information.     

Die Analyse aller bei der Stahlbereitung in Anwendung kommenden Materialien

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Über Konstruktionsprinzipe für die Konstruktion von Helligkeitsgleichen an besonderen Flächenarten

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A network-related nuclear power plant model with an intelligent branch-and-bound solution approach

This paper presents a network model with discrete requirements for a nuclear power plant. The model determines the batch size and timing for nuclear unit refueling and how much energy should be produced by nuclear and non-nuclear units for each time period to satisfy forecasted demand with minimum total operating costs over the planning horizon. Efficient modeling and solution strategies are developed which constitute a merger of operations research and artificial intelligence. A branch-and-bound solution approach is combined with a pattern recognition component, involving non-parametric discrimination analyses, to select branching variables and directions. By coupling this approach with network optimization techniques to exploit the underlying network structure of the problem, substantial improvements are obtained both in solution quality and solution efficiency.This research was supported in part by the Center for Business Decision Analysis, the Hugh Roy Cullen Centennial Chair in Business Administration, and the Office of Naval Research under contract N00014-87-K-0190. Reproduction in whole or in part is permitted for any purpose of the U.S. Government. CENTER FOR BUSINESS DECISION ANALYSIS Darwin Klingman, Director The University of Texas at Austin Austin, TX 78712, U.S.A.     

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Experimental Techniques -     

Zur Trennung des Zinns von Arsen und Antimon

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